Coupling mineralogical analyses, leaching tests and kinetic modelling to unravel groundwater flow-paths in a complex landslide: An attempt from the vedriano case study (northern italian apennines)

As the rise in pore water pressure is one of the main factors in triggering landslides, the understanding of groundwater processes taking place at the hillslope scale is a crucial issue in slope stability analysis. However, identifying flow-paths travelled by water molecules from their infiltration is still a complex task. Hydrochemistry is recognized as a powerful tool that can help to gain useful hydrogeological information and has gradually become increasingly used in addition to conventional study methods. This manuscript presents a comprehensive geochemical investigation consisting of leaching tests and quantitative mineralogical analyses on soil samples, chemical analyses on groundwater samples and modelling. Our results highlighted the usefulness of coupling, even in hydrogeological studies focusing on landslides, geochemical surveys on both water and the soil matrix to constrain the interactions between host-rocks and groundwater. Moreover, it demonstrated that kinetic-based geochemical models, if properly calibrated on leaching tests, can provide valuable information on groundwater dynamics, allowing us to elucidate water-mixing processes beneath the soil surface.