The results on the EXAFS experiments performed on a liquid crystalline copper (II) coordination compound are reported. To the best of our knowledge these are the first results concerning a calamitic liquid crystal. The shell-by-shell data analysis, either in solids or SB mesophase, shows a copper-copper correlation at 3.85 Å, a distance which roughly corresponds to the molecular thickness. These results, together with the X-ray measurements previously carried on a monocrystal, suggest a local biaxial smectic phase.
EXAFS Experiment on a Copper Liquid Crystalline Coordination Compound / Albertini, Gianni; R., Bartolino; M., Ghedini; A., Guido; G., Mancini; S., Stizza. - In: EUROPHYSICS LETTERS. - ISSN 0295-5075. - 12:7(1990), pp. 629-633. [10.1209/0295-5075/12/7/010]
EXAFS Experiment on a Copper Liquid Crystalline Coordination Compound
ALBERTINI, GIANNI;
1990-01-01
Abstract
The results on the EXAFS experiments performed on a liquid crystalline copper (II) coordination compound are reported. To the best of our knowledge these are the first results concerning a calamitic liquid crystal. The shell-by-shell data analysis, either in solids or SB mesophase, shows a copper-copper correlation at 3.85 Å, a distance which roughly corresponds to the molecular thickness. These results, together with the X-ray measurements previously carried on a monocrystal, suggest a local biaxial smectic phase.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.