2,2-Diphenyl-1,2-dihydro-4-ethoxyquinolin-1-yloxyl reacts efficiently with both carbon and oxygen centered (peroxyl, alkoxyl, hydroxyl) radicals leading to products which arise mainly from coupling of radicals with the N-Ȯ function or with the conjugated benzene ring. The reaction with superoxide radical is, however, not very effective, as predicted on the basis of the low reactivity of this radical in typical radical reactions.
Reactivity of 2,2-diphenyl-1,2-dihydro-4-ethoxy-quinoline-1-oxyl towards oxygen- and carbon-centered radicals / Carloni, Patricia; Damiani, Elisabetta; Scattolini, M.; Stipa, Pierluigi; Greci, L.. - In: PERKIN 2. - ISSN 1470-1820. - STAMPA. - 3:(2000), pp. 447-451. [10.1039/a908918g]
Reactivity of 2,2-diphenyl-1,2-dihydro-4-ethoxy-quinoline-1-oxyl towards oxygen- and carbon-centered radicals.
CARLONI, PATRICIA;DAMIANI, Elisabetta;STIPA, Pierluigi;L. GRECI
2000-01-01
Abstract
2,2-Diphenyl-1,2-dihydro-4-ethoxyquinolin-1-yloxyl reacts efficiently with both carbon and oxygen centered (peroxyl, alkoxyl, hydroxyl) radicals leading to products which arise mainly from coupling of radicals with the N-Ȯ function or with the conjugated benzene ring. The reaction with superoxide radical is, however, not very effective, as predicted on the basis of the low reactivity of this radical in typical radical reactions.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
