1-Nitroso-2-naphthol and 2-nitroso-1-naphthol, both in the isonitroso form, react with benzyl bromides in THF and in the presence of triethylamine affording, in low yields, the corresponding O-benzyl oximes and 2-aryl naphthoxazoles in a 1:1 ratio, approximately. The structures of O-benzyl oximes and naphthoxazoles isolated have been determined by X-ray analysis.
Oxazoles Formation During O-Alkylation of Isonitroso-naphthols. X-Ray Structure of [1,2]Naphthoquinone 1-[O-(4-tert-Butyl-benzyl)-oxime] and 2-(4-tert-Butyl-phenyl)Napth[1,2-d]Oxazole
ASTOLFI, PAOLA;CARLONI, PATRICIA;GRECI, Lucedio
;STIPA, Pierluigi
2004-01-01
Abstract
1-Nitroso-2-naphthol and 2-nitroso-1-naphthol, both in the isonitroso form, react with benzyl bromides in THF and in the presence of triethylamine affording, in low yields, the corresponding O-benzyl oximes and 2-aryl naphthoxazoles in a 1:1 ratio, approximately. The structures of O-benzyl oximes and naphthoxazoles isolated have been determined by X-ray analysis.File in questo prodotto:
Non ci sono file associati a questo prodotto.
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
