We demonstrate a proof-of-concept approach for VOC detection based on the mechanical bending of acrylate-based composite polymer films. Under ambient conditions, methanol vapours induce a rapid and reversible defor-mation of the film, which is optically observable and quantitatively described through a viscoelastic three-parameter solid model coupled to pseudo-first- order adsorption kinetics. The bending response differs markedly between methanol, water, and mixed vapours, revealing a strong dependence on sur-face adsorption dynamics. The acrylate backbone is identified as the active sensing layer, capable of transducing molecular interactions into macroscopic deflection. These findings establish acrylate polymers as a simple, low-cost platform for passive VOC-responsive materials and highlight their potential for future development into calibrated sensing devices.

Methanol-detection by acrylate-based composite polymer film actuation / Castagna, Riccardo; Riminesi, Cristiano; Lucchetta, Daniele E.; Papa, Fabrizio; Singh, Gautam; Da Prada, Mario; Di Donato, Andrea. - In: OPTICAL MATERIALS. - ISSN 0925-3467. - 175:(2026). [10.1016/j.optmat.2026.117946]

Methanol-detection by acrylate-based composite polymer film actuation

Castagna, Riccardo
;
Lucchetta, Daniele E.;Di Donato, Andrea
2026-01-01

Abstract

We demonstrate a proof-of-concept approach for VOC detection based on the mechanical bending of acrylate-based composite polymer films. Under ambient conditions, methanol vapours induce a rapid and reversible defor-mation of the film, which is optically observable and quantitatively described through a viscoelastic three-parameter solid model coupled to pseudo-first- order adsorption kinetics. The bending response differs markedly between methanol, water, and mixed vapours, revealing a strong dependence on sur-face adsorption dynamics. The acrylate backbone is identified as the active sensing layer, capable of transducing molecular interactions into macroscopic deflection. These findings establish acrylate polymers as a simple, low-cost platform for passive VOC-responsive materials and highlight their potential for future development into calibrated sensing devices.
2026
Volatile organic compounds (VOCs), Polymer-film actuatorSensors, Photo-mobile polymer films, PMPsMethanol-responsive bending
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11566/354472
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