Fatty acid methyl esters (FAME) and glycerol produced by transesterification reaction contain atoms that in the reagents belong to methanol and, therefore, are not renewable. A method to evaluate the content of the renewable and non-renewable energetic fraction, released during their combustion, was developed using a thermochemical criteria, based on bond dissociation energies and the knowledge of the molecular structure of the reagents and the products. Results show that the fraction of non-renewable. Energy in the most diffused FAME is lower than 1% depending on the lengths of the carbonaceous methyl esters. Meanwhile, the energetic supply for the GL of this fraction is about 1.6%. The data reported in this document can be used to develop a criteria that corrects the fiscal mechanism aspects of some renewable energy products.

Renewable energy content of fatty acid methyl esters (FAME and glycerol) / Toscano, Giuseppe; Duca, Daniele. - In: JOURNAL OF AGRICULTURAL ENGINEERING. - ISSN 1974-7071. - (2009), pp. 47-53.

Renewable energy content of fatty acid methyl esters (FAME and glycerol)

TOSCANO, Giuseppe;DUCA, DANIELE
2009-01-01

Abstract

Fatty acid methyl esters (FAME) and glycerol produced by transesterification reaction contain atoms that in the reagents belong to methanol and, therefore, are not renewable. A method to evaluate the content of the renewable and non-renewable energetic fraction, released during their combustion, was developed using a thermochemical criteria, based on bond dissociation energies and the knowledge of the molecular structure of the reagents and the products. Results show that the fraction of non-renewable. Energy in the most diffused FAME is lower than 1% depending on the lengths of the carbonaceous methyl esters. Meanwhile, the energetic supply for the GL of this fraction is about 1.6%. The data reported in this document can be used to develop a criteria that corrects the fiscal mechanism aspects of some renewable energy products.
2009
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11566/35109
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