Three-dimensional (3D) graphene-based architectures can combine the two-dimensional properties of graphene with the high surface-to-volume ratio required for a large variety of technological applications. We present a spectro-microscopy study of stable microporous 3D few-layer graphene structures with a very low density of defects/edges and of unsaturated bonds, as deduced by Raman and core level photoemission spectroscopy. These qualities make these interconnected graphene networks ideal candidates to accommodate lithium adatoms, with a high density of Li per unit volume and a Li uptake per C atom higher than the value observed for graphite, as confirmed by core level photoemission spectroscopy.

Three-dimensional microporous graphene decorated with lithium / Iacobucci, M.; Bernardo, I. D.; Christian, M.; Morandi, V.; Ripanti, F.; Postorino, P.; Mariani, C.; Betti, M. G.. - In: NANOTECHNOLOGY. - ISSN 0957-4484. - 29:40(2018), p. 405707. [10.1088/1361-6528/aad3f5]

Three-dimensional microporous graphene decorated with lithium

Ripanti F.;
2018-01-01

Abstract

Three-dimensional (3D) graphene-based architectures can combine the two-dimensional properties of graphene with the high surface-to-volume ratio required for a large variety of technological applications. We present a spectro-microscopy study of stable microporous 3D few-layer graphene structures with a very low density of defects/edges and of unsaturated bonds, as deduced by Raman and core level photoemission spectroscopy. These qualities make these interconnected graphene networks ideal candidates to accommodate lithium adatoms, with a high density of Li per unit volume and a Li uptake per C atom higher than the value observed for graphite, as confirmed by core level photoemission spectroscopy.
2018
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11566/323651
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