Mesomorphic [Ag(2)][TfO] (TfO=CF3SO3) and [Ag(2)][TsO] (TsO=p-CH3C6H4SO3) have been prepared by silver complexation of the novel N,N'-bis(hexadecanoyl)-1,10-diaza-4,7,13,16-tetrathiacyclooctadecane, 2. The phase behaviour of the silver complexes is described and a lamellar mesophase is proposed for [Ag(2)][TfO] by means of X-ray evidence.
Macrocyclic Metallomesogens: Thermotropic Double-chained Silver Amphiphiles / F., Neve; M., Ghedini; Francescangeli, Oriano. - In: JOURNAL OF MATERIALS CHEMISTRY. - ISSN 0959-9428. - 5 (6):(1995), pp. 931-932. [10.1039/jm9950500931]
Macrocyclic Metallomesogens: Thermotropic Double-chained Silver Amphiphiles
FRANCESCANGELI, ORIANO
1995-01-01
Abstract
Mesomorphic [Ag(2)][TfO] (TfO=CF3SO3) and [Ag(2)][TsO] (TsO=p-CH3C6H4SO3) have been prepared by silver complexation of the novel N,N'-bis(hexadecanoyl)-1,10-diaza-4,7,13,16-tetrathiacyclooctadecane, 2. The phase behaviour of the silver complexes is described and a lamellar mesophase is proposed for [Ag(2)][TfO] by means of X-ray evidence.File in questo prodotto:
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