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EnglishBent-core liquid crystals showing a nematic phase stable at low temperatures are very attractive for applicative purposes in view of the inherent biaxial nature of the nematic phase. In this work, a typical five-ring bent-core mesogen was investigated by means of2H NMR spectroscopy and X-ray diffraction (XRD) methods. These techniques provide complementary information on the structural properties of the nematic phase and the average mesogen conformation: Small-angle XRD reveals the presence of short-range positional order in the form of skewed cybotaxis, while a comparison of the orientational order parameters measured by wide-angle XRD and NMR provides an estimate of the molecule bend angle. In addition, 2H NMR puts in evidence the occurrence of an unexpected transition to a low-temperature tilted phase, having a crystalline or smectic-like character. The results were compared with those of previous 13C NMR investigations.
| Titolo: | Comparative 2H NMR and x-ray diffraction investigation of a bent-core liquid crystal showing a Nematic phase | |
| Autori: | ||
| Data di pubblicazione: | 2020 | |
| Rivista: | ||
| Abstract: | Bent-core liquid crystals showing a nematic phase stable at low temperatures are very attractive for applicative purposes in view of the inherent biaxial nature of the nematic phase. In this work, a typical five-ring bent-core mesogen was investigated by means of2H NMR spectroscopy and X-ray diffraction (XRD) methods. These techniques provide complementary information on the structural properties of the nematic phase and the average mesogen conformation: Small-angle XRD reveals the presence of short-range positional order in the form of skewed cybotaxis, while a comparison of the orientational order parameters measured by wide-angle XRD and NMR provides an estimate of the molecule bend angle. In addition, 2H NMR puts in evidence the occurrence of an unexpected transition to a low-temperature tilted phase, having a crystalline or smectic-like character. The results were compared with those of previous 13C NMR investigations. | |
| Handle: | http://hdl.handle.net/11566/281600 | |
| Appare nelle tipologie: | 1.1 Articolo in rivista |
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