Soil leaching column chromatography (SLCC) employing totally aqueous mobile phases has been used for the estimation of retardation factors (R) of heterocyclic compounds and heteroatom-substituted aryl derivatives Aniline, Aniside, Cresol, Hydroquinone, p-Nitroaniline, Phenol, Phenylenediamine, Piridine, Sulfanilamide, Sulfathiazole, Sulfamethoxazole, Metolachlor and Toluene in soils with low fraction of organic carbon. Small columns (0.39 cm x 10 cm i.d.) were packed with soils of different compositions (alluvial sediment, coarse sand and standard Eurosoil4 mixed with quartz). The theory of linear chromatography was employed to correlate statistical peak moments to R. Rs estimated through SLCC were compared with those derived from water-organic carbon partitioning coefficient reported in the literature. The adsorption isotherm of Metolachlor was measured by frontal analysis on a small column packed with alluvial sediment. The approach proposed for measuring the adsorption isotherm requires small amounts of chemicals and soils and does not need fraction collection nor detector calibration. The information obtained by SLCC experiments was used to predict the elution of Metolachlor and Phenol on a large column (8.9 cm x 100 cm i.d.) packed with alluvial sediment. The method used in this work, not making use of any chemical solvents, respects the fundamental concepts of green chemistry.

A green and fast chromatographic method for determining organic compound mobility in soils / Mastrocicco, Micòl; Colombani, Nicolò; Cavazzini, Alberto; Pasti, Luisa. - In: JOURNAL OF CHROMATOGRAPHY A. - ISSN 0021-9673. - ELETTRONICO. - 1216:40(2009), pp. 6802-6809. [10.1016/j.chroma.2009.08.006]

A green and fast chromatographic method for determining organic compound mobility in soils

Colombani, Nicolò
Writing – Original Draft Preparation
;
2009-01-01

Abstract

Soil leaching column chromatography (SLCC) employing totally aqueous mobile phases has been used for the estimation of retardation factors (R) of heterocyclic compounds and heteroatom-substituted aryl derivatives Aniline, Aniside, Cresol, Hydroquinone, p-Nitroaniline, Phenol, Phenylenediamine, Piridine, Sulfanilamide, Sulfathiazole, Sulfamethoxazole, Metolachlor and Toluene in soils with low fraction of organic carbon. Small columns (0.39 cm x 10 cm i.d.) were packed with soils of different compositions (alluvial sediment, coarse sand and standard Eurosoil4 mixed with quartz). The theory of linear chromatography was employed to correlate statistical peak moments to R. Rs estimated through SLCC were compared with those derived from water-organic carbon partitioning coefficient reported in the literature. The adsorption isotherm of Metolachlor was measured by frontal analysis on a small column packed with alluvial sediment. The approach proposed for measuring the adsorption isotherm requires small amounts of chemicals and soils and does not need fraction collection nor detector calibration. The information obtained by SLCC experiments was used to predict the elution of Metolachlor and Phenol on a large column (8.9 cm x 100 cm i.d.) packed with alluvial sediment. The method used in this work, not making use of any chemical solvents, respects the fundamental concepts of green chemistry.
2009
File in questo prodotto:
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11566/267555
 Attenzione

Attenzione! I dati visualizzati non sono stati sottoposti a validazione da parte dell'ateneo

Citazioni
  • ???jsp.display-item.citation.pmc??? 0
  • Scopus 6
  • ???jsp.display-item.citation.isi??? 5
social impact